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20220616031744.0 |
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080219t20082008njua b 001 0 eng |
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|a 2008007592
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|a 0470262028 (cloth)
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|a 9780470262023 (cloth)
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|a (OCoLC)212015645
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|a DLC
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|b .S95 2008
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| 082 |
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|a 541/.395
|2 22
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| 100 |
1 |
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|a Swiegers, Gerhard F.
|0 http://id.loc.gov/authorities/names/n2008011939
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| 245 |
1 |
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|a Mechanical catalysis :
|b methods of enzymatic, homogeneous, and heterogeneous catalysis /
|c Gerhard F. Swiegers.
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| 260 |
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|a Hoboken, N.J. :
|b John Wiley,
|c [2008], ©2008.
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| 300 |
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|a xxx, 351 pages :
|b illustrations ;
|c 25 cm
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| 336 |
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|a text
|b txt
|2 rdacontent
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| 337 |
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|a unmediated
|b n
|2 rdamedia
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| 338 |
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|a volume
|b nc
|2 rdacarrier
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| 504 |
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|a Includes bibliographical references and index.
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|a Introduction to thermodynamic (energy-dependent) and mechanical (time-dependent) processes : What are they and how are they manifested in chemistry and catalysis? / Gerhard F. Swiegers -- Heterogeneous, homogeneous, and enzymatic catalysis ; A shared terminology and conceptual platform ; The alternative of time-dependence in catalysis / Gerhard F. Swiegers -- A conceptual description of energy-dependent ("Thermodynamic") and time-dependent ("Mechanical") processes in chemistry and catalysis / Gerhard F. Swiegers -- Time-dependence in heterogeneous catalysis ; Sabatier's principle describes two independent catalytic realms: time-dependent ("Mechanical") catalysis and energy-dependent ("Thermodynamic") catalysis / Gerhard F. Swiegers -- Time-dependence in homogeneous catalysis. 1. Many enzymes display the hallmarks of time-dependent ("Mechanical") catalysts ; Nonbiological homogeneous catalysts are typically energy-dependent ("Thermodynamic") catalysts / Robin Brimblecombe, Jun Chen, Junhua Huang, Ulrich T. Mueller-Westerhoff, and Gerhard F. Swiegers -- Time-dependence in homogeneous catalysis. 2. The general actions of time-dependent ("Mechanical") and energy-dependent ("Thermodynamic") catalysts / Robin Brimblecombe, Jun Chen, Junhua Huang, Ulrich T. Mueller-Westerhoff, and Gerhard F. Swiegers -- Unifying the many theories of enzymatic catalysis ; Theories of enzymatic catalysis fall into two camps: energy-dependent ("Thermodynamic") and time-dependent ("Mechanical") catalysis / Gerhard F. Swiegers -- Synergy in heterogeneous, homogeneous, and enzymatic catalysis ; The "Ideal" catalyst / Gerhard F. Swiegers -- A conceptual unification of heterogeneous, homogeneous, and enzymatic catalysis / Gerhard F. Swiegers -- The rational design of time-dependent ("Mechanical") homogeneous catalysts ; A literature survey of multi-centered homogeneous catalysis / Junhua Huang, and Gerhard F. Swiegers -- Time-dependent ("Mechanical") nonbiological catalysis. 1. A fully-functional mimic of the water-oxidizing center (WOC) in photosystem II (PSII) / Robin Brimblecombe, G. Charles Dismukes, Greg A. Felton, Leone Spiccia, and Gerhard F. Swiegers -- Time-dependent ("Mechanical") nonbiological catalysis. 2. Highly efficient, "Biomimetic" hydrogen-generating electrocatalysts / Jun Chen, Junhua Huang, Gerhard F. Swiegers, Chee O. Too, and Gordon G. Wallace -- Time-dependent ("Mechanical") nonbiological catalysis. 3. A readily prepared, convergent, oxygen-reduction electrocatalyst / Jun Chen, Gerhard F. Swiegers, Gordon G. Wallace, and Weimin Zhang -- Appendix A. Why is saturation not observed in catalysts that display conventional kinetics -- Appendix B. Graphical illustration of the processes involved in the saturation of molecular catalysts.
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|a Heterogeneous catalysis.
|0 http://id.loc.gov/authorities/subjects/sh85060532
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| 650 |
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|a Catalysis.
|0 http://id.loc.gov/authorities/subjects/sh85020938
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| 650 |
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|a Enzymes
|x Biotechnology.
|0 http://id.loc.gov/authorities/subjects/sh2008119805
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| 856 |
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|z Connect to: Table of contents only - All users
|u http://catdir.loc.gov/catdir/enhancements/fy0811/2008007592-t.html
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