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120516s2012 gw | o |||| 0|eng d |
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|z 9783642293801
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|z 9783642426742
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|a 9781280792441 (online)
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|a 9783642293818 (online)
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|a QD95-96
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|a Brogaard, Rasmus Y.
|e author.
|4 aut
|4 http://id.loc.gov/vocabulary/relators/aut
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|a Molecular Conformation and Organic Photochemistry
|h [electronic resource]
|b Time-resolved Photoionization Studies /
|c by Rasmus Y. Brogaard.
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| 250 |
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|a 1st ed. 2012.
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| 264 |
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1 |
|a Berlin, Heidelberg :
|b Springer Berlin Heidelberg :
|b Imprint: Springer,
|c 2012.
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| 490 |
1 |
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|a Springer Theses, Recognizing Outstanding Ph.D. Research,
|x 2190-5061
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| 505 |
0 |
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|a Aspects and investigation of photochemical dynamics -- A time-resolved probing method: photoionization -- Simulation of time-resolved photoionization signals -- Simulation: the Norrish type-I reaction in acetone -- Experimental setups -- Paracyclophanes I: [2+2]cycloaddition of ethylenes -- Paracyclophanes II: The Paternò-Büchi reaction -- Probing structural dynamics by interaction between chromophores.
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|a Rasmus Brogaard's thesis digs into the fundamental issue of how the shape of a molecules relates to its photochemical reactivity. This relation is drastically different from that of ground-state chemistry, since lifetimes of excited states are often comparable to or even shorter than the time scales of conformational changes. Combining theoretical and experimental efforts in femto-second time-resolved photoionization Rasmus Brogaard finds that a requirement for an efficient photochemical reaction is the prearrangement of the constituents in a reactive conformation. Furthermore, he is able to show that by exploiting a strong ionic interaction between two chromophores, a coherent molecular motion can be induced and probed in real-time. This way of using bichromophoric interactions provides a promising strategy for future research on conformational dynamics.
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| 650 |
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|a Spectrum analysis.
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| 650 |
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|a Atomic structure .
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| 650 |
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|a Molecular structure .
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| 650 |
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|a Physical chemistry.
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| 710 |
2 |
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|a SpringerLink (Online service)
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| 773 |
0 |
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|t Springer English/International eBooks 2012 - Full Set
|d Springer Nature
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| 776 |
0 |
8 |
|i Printed edition:
|z 9783642293825
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| 776 |
0 |
8 |
|i Printed edition:
|z 9783642426742
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| 776 |
0 |
8 |
|i Printed edition:
|z 9783642293801
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| 776 |
1 |
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|t Molecular Conformation and Organic Photochemistry
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| 830 |
|
0 |
|a Springer Theses, Recognizing Outstanding Ph.D. Research,
|x 2190-5061
|
| 856 |
4 |
0 |
|y Access Content Online(from Springer English/International eBooks 2012 - Full Set)
|u https://ezproxy.msu.edu/login?url=https://link.springer.com/10.1007/978-3-642-29381-8
|z Springer English/International eBooks 2012 - Full Set: 2012
|
